Answer for cyclohexane:
At 20°C the physical state of cyclohexane will be liquid.
Explanation for cyclohexane:
The boiling point of a substance is the temperature at which it changes from a liquid state to a gaseous atate.
If 80.7°C is the boiling point of cyclohexane, it means that at that temperature it changes state from liquid to gaseous.
If the temperature is lower than 80.7°C the cyclohexane will remain at liquid state, and if the temperature is greater than 80.7°C its state will be gaseous.
So, at 20°C the physical state of cyclohexane will be liquid.