We can answer this question as follows:
Case A:
Segment AB is congruent to segment DC. That is always true. The opposite sides of a parallelogram are congruent.
Case B:
Segment BC is congruent to segment AD. That is always true. The opposite sides of a parallelogram are congruent.
Case C:
This is NOT always true. What is true is that consecutive pairs of angles of a parallelogram are supplementary. For example,
Case D:
AB+BC=AD+DC. This is always true. The diagonal that goes from vertex A to vertex C divides the parallelogram into two congruent triangles. Therefore, this statement is always true.
Therefore, the option that is NOT always true is Angle A and angle C are supplementary (add to 180) (option C).