We are given the following information
Mass of objects: m = 4.72 kg
Distance between objects: r = 3.12 m
Charge: q = 85.5 μC
We are asked to find the initial acceleration of each mass.
Recall from Newton's second law of motion,

Where F is the force between two masses, m is the mass, and a is the acceleration.
First, let us find the force between the two masses.
Recall from Coulomb's law,

Where k is the Coulomb's law constant that is k = 9×10⁹ Nm²/C²
Substitute the given values into the above formula

Finally, the initial acceleration of each mass is

Therefore, the initial acceleration of each mass is 1.43 m/s^2