Here we have a 0.25 M solution.
Remember M or molarity is the moles per liters of solution.
Solute = potassium bromide KBr
0.25 mol/L: 0.25 moles of KBr ------- 1 L of solution
Now, let's find the volume:
0.25 moles of KBr ------- 1 L of solution
0.53 moles of KBr ------- X
X = 2.12 L
Answer: V = 2.12 L