The average acceleration a of an object that changes its speed from v_0 to v_f during a time interval t is:

Since the car is initially moving at 25.0m/s and it stops in 3.00 seconds, then its final speed is 0m/s.
Replace v_f=0, v_0=25.0m/s and t=3.00s to find the average acceleration of the car:

Therefore, the average acceleration of the car when it stops from 25.0m/s in 3.00 seconds, is -8.33m/s^2.