First, you need to transform grams of NaCl into moles of NaCl. For this, you will divide by its molar mass. If you divide a fraction, If you divide a fraction, it is inverted and multiplied. So first you have:
0.75 g NaCl x 1 mol NaCl / 58.4 g/mol NaCl = 1.28 x 10^-2 moles
Now you need to use the avogrado's constant to find the number of particles. The avogrado's constant value is 6.02x10^23 mol^-1.
So you have:
0.75 g NaCl x 1 mol NaCl / 58.4 g/mol NaCl x 6.02 x 10^23 particles NaCl / 1 mol NaCl = 7.73 x 10^21 particles of NaCl