Let the particular student be named A.
There are total 45 students, so the number of students other than A will be 44.
The experiment is to select a student.
Favourable event: The particular student is selected, that is, A gets selected.
There is only 1 way to select A from the total students.
The probability of any event is given by,

So the probability that the particular student (A) is selected is given by,

Thus, the required probability is 2.22% approximately.
Therefore, the 4th option is the correct choice.