This is an exercise in the general or combined gas law.
To start solving this exercise, we obtain the following data:
Data:
- T₁ = 22.5 °C + 273 = 295.5 K
- P₁ = 1.95 atm
- V₁ = ¿?
- P₂ = 3.69 atm
- T₂ = 11.9 °C + 273 = 284.9 k
- V₂= 56.4 ml
We use the following formula:
P₁V₁T₂ = P₂V₂T₁ ⇒ General formula
Where
- P₁ = Initial pressure
- V₁ = Initial volume
- T₂ = Initial temperature
- P₂ = Final pressure
- V₂ = final volume
- T₁ = Initial temperature
We clear the formula for the initial volume:
![\boldsymbol{\sf{V_(1)=(P_(2)V_(2)T_(1))/(P_(1)T_(2)) } }](https://img.qammunity.org/2023/formulas/chemistry/college/o3o5mmcthl1qifp9paicsxio49wvwomi5s.png)
We substitute our data into the formula to solve:
![\boldsymbol{\sf{V_(1)=\frac{(3.69 \\ot{atm})(56.4 \ ml)(295.5 \\ot{k})}{(1.95 \\ot{atm})(284.9\\ot{k})} }}](https://img.qammunity.org/2023/formulas/chemistry/college/ksnt94gd29uo7ee5jsx8n61oao8l2uz8nm.png)
![\boldsymbol{\sf{V_(1)=(61498.278)/(555.555) \ lm }}](https://img.qammunity.org/2023/formulas/chemistry/college/xwatm8x9guhfbjcyriodyhcj399s7x58cf.png)
![\boxed{\boldsymbol{\sf{V_(1)=110.697 \ lm }}}](https://img.qammunity.org/2023/formulas/chemistry/college/7wfgp7fp83sl32wplnl9p07dya1xlrw1sm.png)
The helium-filled balloon has a volume of 110.697 ml.