Answer:
11.25 mL
Step-by-step explanation:
To determine the volume of concentrated hydrobromic acid (HBr) needed to prepare a 0.449 M solution with a total volume of 75.0 mL, we can use the following equation:
```
M1 * V1 = M2 * V2
```
where:
* M1 is the molarity of the concentrated solution
* V1 is the volume of the concentrated solution
* M2 is the molarity of the dilute solution
* V2 is the volume of the dilute solution
Substituting the known values into the equation, we get:
```
3.00 M * V1 = 0.449 M * 75.0 mL
```
```
V1 = (0.449 M * 75.0 mL) / 3.00 M
```
```
V1 = 11.25 mL
```
Therefore, 11.25 mL of concentrated HBr is needed to prepare a 0.449 M solution with a total volume of 75.0 mL.
**Answer:** 11.25 mL