Option 3 is the correct choice. The difference in bonding type (ionic vs. covalent) and the associated bond strength is the primary reason for the significant difference in melting points between MgO and NaF.
The primary reason for the significant difference in melting points between MgO and NaF is their difference in bonding type and strength. Let's break down each option step by step:
Option 1: MgO has a lower density than NaF.
- Density alone is not the primary factor determining melting points. Melting points are primarily determined by the strength and type of chemical bonds between atoms or ions in a substance.
Option 2: NaF has a more complex crystal structure.
- The complexity of the crystal structure can influence melting points to some extent, but it is not the primary reason for the significant difference in melting points between MgO and NaF.
Option 3: MgO exhibits ionic bonding, whereas NaF exhibits covalent bonding.
- This is the correct answer. Ionic bonds are typically stronger than covalent bonds, and this difference in bond strength directly affects the melting points of compounds. In MgO, there are strong ionic bonds between magnesium (Mg²⁺) and oxygen (O²⁻) ions, whereas in NaF, there are covalent bonds between sodium (Na⁺) and fluorine (F⁻) atoms. Ionic bonds tend to require more energy to break, leading to higher melting points.
Option 4: NaF molecules are larger in size than MgO molecules.
- This is not a significant factor in determining melting points. The size of the molecules or ions in a substance can affect physical properties, but it's not the primary reason for the difference in melting points between these two compounds.