Final answer:
Sample A is likely a mixture because of the varied properties it showed when dissolved in ethanol. Sample B is likely a pure substance based on its consistent behavior when it was dissolved in water.
Step-by-step explanation:
Based on the provided information, Sample A exhibits the characteristics of a mixture. This is supported by the occurrences when it's subjected to certain processes, such as dissolving in ethanol and subsequent changes in color (from black to deep purple and then a green ring around the stain).
Mixtures often show varied properties throughout different parts as their components do not combine chemically.
Sample B can be considered a pure substance. This is evident from its consistent behavior when dissolved in water, and the small divergence in the volume of water required to dissolve equal masses can be attributed to experimental errors.
Pure substances show consistent properties because they have the same composition throughout.
Learn more about Differentiating Mixtures and Pure Substances