Final answer:
By applying Dalton's law of partial pressures, the total pressure after adding a third gas to a mixture of two gases in a container is found by summing the individual partial pressures. After calculating the partial pressure of the third gas using the ideal gas law, the total pressure in the container is approximately 1.372 atm.
Step-by-step explanation:
To find the total pressure in the container after adding a third gas, we can apply Dalton's law of partial pressures which states that the total pressure of a mixture of gases is equal to the sum of their individual partial pressures.
Initially, we have the partial pressures of gas A and gas B, which are 0.323 atm and 0.660 atm, respectively. The pressure of the third gas can be found using the ideal gas law:
PV = nRT
For the third gas, at a fixed volume (8.25 L) and temperature (21°C), and with a known amount (0.130 mol), we can calculate its partial pressure.
However, we need the value of R (the ideal gas constant) and we need to convert the temperature to Kelvins. Assuming R = 0.0821 L·atm/(mol·K), and converting the temperature to Kelvins (294.15 K), we can calculate the partial pressure of the third gas.
P = nRT/V
P = (0.130 mol)(0.0821 L·atm/(mol·K))(294.15 K) / (8.25 L) = 0.389 atm (approx.)
We can now sum the partial pressures to find the total pressure.
Ptot = 0.323 atm + 0.660 atm + 0.389 atm = 1.372 atm
The total pressure in the container after adding the third gas at the same volume and temperature is approximately 1.372 atm.