Answer: 5/12
Step-by-step explanation
Let's say a "3" is rolled on cube A. That would mean cube B would need to roll a "1" or "2", so the result of A is larger than B.
This idea is applied to the other possible rolls to generate this table.

We have 1+2+3+4+5 = 15 different cases where the result of A is larger than the result of B. This is out of 6*6 = 36 ways to roll two dice.
Therefore, we have a probability of 15/36 = 5/12 where A > B.
5/12 = 0.4167 = 41.67% approximately