Final answer:
The pH of a 3M solution of HNO3 is approximately 0, as the strong acid ionizes completely, yielding a hydronium ion concentration equal to the molarity of the acid.
Step-by-step explanation:
The pH of a solution is a measure of its acidity or basicity. For a strong acid like HNO3, which ionizes completely in water, the concentration of hydronium ions ([H3O+]) is equal to the molarity of the acid. Given a 3M solution of HNO3, the hydronium ion concentration is also 3M. To calculate the pH, you take the negative logarithm of the hydronium ion concentration. Thus, pH = -log(3) which approximately equals -0.477. However, since pH cannot be negative, we must understand that a high acid concentration can result in a pH that approaches zero. Therefore, the pH of a 3M solution of HNO3 is approximately 0.