The heat required to convert 25.0 g of C2Cl3F3 from a liquid at 5.00°C to a gas at 82.00°C can be calculated as follows:
1. The heat required to raise the temperature of the liquid from 5.00°C to 47.60°C is:
```
heat_liquid = 25.0 g * 0.91 J/g-K * (47.60°C - 5.00°C) = 948.5 J
```
2. The heat of vaporization of C2Cl3F3 is:
```
heat_vaporization = 25.0 g * 3.667 kJ/g = 91.675 kJ
```
3. The heat required to raise the temperature of the gas from 47.60°C to 82.00°C is:
```
heat_gas = 25.0 g * 0.67 J/g-K * (82.00°C - 47.60°C) = 338.5 J
```
4. The total heat required is the sum of the three heats calculated above:
total_heat = heat_liquid + heat_vaporization + heat_gas = 948.5 J + 91.675 kJ + 338.5 J = 1378.675 kJ
Therefore, the heat required to convert 25.0 g of C2Cl3F3 from a liquid at 5.00°C to a gas at 82.00°C is 1378.675 kJ.