Since AD = BC, we know that angles A and B are congruent, and angles C and D are congruent as well. Let's call the measure of angle A (and angle B) "x," and the measure of angle C (and angle D) "y."
Since ABCD is an isosceles trapezoid, we know that angles A and B add up to 180 degrees, as do angles C and D. Therefore, we have:
x + x + y + y = 180
Simplifying this equation, we get:
2x + 2y = 180
Dividing both sides by 2, we get:
x + y = 90
So the sum of the measures of angles A and C is 90 degrees. Therefore, mLA + mZC = 90 degrees, which corresponds to answer choice (B).