Answer: First, let's define the terms used in thermodynamics:
ΔE: Change in internal energy of the system.
ΔH: Change in enthalpy of the system.
q: Heat added to or removed from the system.
w: Work done by or on the system.
For a process at constant pressure (such as burning at constant pressure), we have the following relationships:
ΔH = q (Enthalpy change is equal to the heat added or removed at constant pressure)
ΔE = q - w (Change in internal energy is equal to the heat added or removed minus the work done)
Given:
q = 2422 J (heat added to the system, positive because heat is added)
w = 6 kJ = 6000 J (work done by the system on the surroundings, positive because work is done on the surroundings)
Now, let's calculate the values:
ΔE = q - w = 2422 J - 6000 J ≈ -3580 J ≈ -4 × 10^3 J (to one significant figure)
ΔH = q = 2422 J (to four significant figures)
q = 2422 J (to four significant figures)
w = 6000 J (to one significant figure)
So, the answers are:
- ΔE ≈ -4 × 10^3 J (one significant figure)
- ΔH = 2422 J (four significant figures)
- q = 2422 J (four significant figures)
- w = 6000 J (one significant figure)