Answer and Explanation:
According to Le Chatelier's principle, the correct statement is B) The equilibrium constant changes with a change in temperature.
Le Chatelier's principle states that when a system at equilibrium is subjected to a change in temperature, pressure, or concentration, the system will adjust to counteract the change and reestablish equilibrium. In the case of a change in temperature, the equilibrium constant (K) of a chemical reaction can be affected.
When the temperature of a system at equilibrium increases, the reaction is considered endothermic, meaning it absorbs heat. To counteract the increase in temperature, the system will shift in the direction that absorbs heat. This results in a change in the concentrations of the reactants and products, which affects the equilibrium constant.
Conversely, when the temperature decreases, the reaction is considered exothermic, meaning it releases heat. The system will shift in the direction that releases heat to counteract the decrease in temperature. Again, this affects the concentrations of the reactants and products, thus changing the equilibrium constant.
Therefore, it is true that the equilibrium constant changes with a change in temperature, as stated in option B.