Final answer:
The change in internal energy of the system is -45.855 kJ; when rounded to one decimal place, it is -45.9 kJ, corresponding to answer option d.
Step-by-step explanation:
To calculate the change in internal energy (ΔE) of a system, you can use the first law of thermodynamics, which states that the change in internal energy of a system is equal to the heat added to the system minus the work done by the system on its surroundings: ΔE = Q - W. In this case, 45.0 kJ of heat is released (Q = -45.0 kJ because heat is going out of the system) and the system is performing 855 J of work on the surroundings (W = 855 J because the work is done by the system).
First, we convert the work done from joules to kilojoules (since the heat is in kilojoules): 855 J = 0.855 kJ. Now we can use the formula with consistent units:
ΔE = Q - W = (-45.0 kJ) - (0.855 kJ) = -45.855 kJ
The change in internal energy of the system is -45.855 kJ, which, rounded to one decimal place, would be -45.9 kJ. Therefore, the correct answer is option d. -45.9 kJ.