Final answer:
Land breezes and valley breezes both occur at night due to the rapid cooling of the land in comparison to water and mountain slopes compared to valleys, both creating pressure differences that drive the breezes.
Step-by-step explanation:
Land breezes and valley breezes both occur at night. These breezes are the result of differential heating and cooling rates of the land versus water or the mountain versus the valley. Specifically, water has a higher specific heat capacity than land, meaning it takes longer to heat up during the day and longer to cool down at night. During the day, the land heats up more quickly than the water, causing air over the land to warm and rise, creating a low-pressure area. Cooler, higher-pressure air from the water then moves in to replace it, creating a sea breeze. At night, the opposite occurs. The land cools down more quickly than the water, creating a high-pressure area over the cooler land and a low-pressure area over the warmer water, allowing a land breeze to blow from the land toward the water. Similarly, after sunset, the air over the mountain slopes also cools more quickly, creating a high-pressure area that sends cooler air down into the valley, resulting in a valley breeze.