To summarize: arteries and veins differ in terms of their structure, direction of blood flow, presence of valves, oxygenation, blood pressure, blood volume, and appearance. Arteries carry oxygenated blood away from the heart, have thicker walls, higher pressure, and no valves, while veins carry deoxygenated blood towards the heart, have thinner walls, lower pressure, and contain valves to ensure one-way blood flow.