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Explain about Huckel Approximation ( the introduction to the method including secular equation and determinant, theory that could be used to evaluate or assumptions, characteristic such as all overlap integrals are set equal to zero etc , the matrix formulation of the huckel method and mustification of the formula).

User ManIkWeet
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The Hückel approximation, also known as the Hückel method, is a simplified quantum mechanical approach used to study the electronic structure of conjugated π-electron systems in organic molecules. It provides valuable insights into the electronic properties and stability of these systems.

The Hückel method makes several assumptions:
1. π-electrons are the only electrons of interest in the molecule.
2. The π-electrons are delocalized over the conjugated system.
3. All overlap integrals between atomic orbitals (AOs) are set to zero except for adjacent carbon atoms.
4. The π-electrons experience a constant effective potential throughout the molecule, which approximates the average potential felt by the electrons.
5. The wavefunction of each π-electron can be approximated as a linear combination of atomic orbitals.

The Hückel method is based on the secular equation, which relates the molecular orbital energies to the coefficients of the linear combination of atomic orbitals. The secular equation can be written as:

det(H - E*S) = 0

In this equation, H is the Hamiltonian matrix representing the energy of the molecular orbitals, E is the energy eigenvalue (molecular orbital energy), and S is the overlap matrix representing the overlap between atomic orbitals. The determinant of the matrix equation determines the eigenvalues (energies) of the molecular orbitals.

The matrix formulation of the Hückel method can be written as:

H * C = E * S * C

In this equation, H is the Hückel matrix, C represents the coefficient vector of the linear combination of atomic orbitals, E is the eigenvalue (molecular orbital energy), and S is the overlap matrix.

The justification for the Hückel method comes from the fact that for conjugated π-electron systems, the interactions between adjacent carbon atoms dominate the electronic structure. By neglecting overlap integrals between non-adjacent atoms and considering a constant effective potential, the Hückel method simplifies the calculations while still providing reasonable approximations for the electronic properties of these systems.

The Hückel method has been widely used in the field of theoretical organic chemistry to predict and understand the behavior of conjugated systems, such as aromatic compounds and conjugated polymers. It provides insights into molecular orbital energies, bond orders, and aromaticity, helping in the interpretation of chemical reactivity and stability of these systems.
User Luke Tierney
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