Okay, let's break this down step-by-step:
* We are given:
- Initial volume: 725 ml
- Initial pressure: 825 torr
- Temperature is constant
* The key relationship we can use is Boyle's Law:
P1V1 = P2V2
Where:
P1 = initial pressure
V1 = initial volume
P2 = final pressure (what we want to calculate)
V2 = final volume
* For part (a), the final volume is 359 ml. Plugging into Boyle's Law:
825 torr * 725 ml = P2 * 359 ml
P2 = (825 torr * 725 ml) / 359 ml = 1698 torr
The new pressure will be 1698 torr when the volume changes to 359 ml.
* For part (b), the final volume is 4.94 L. Converting to ml, that is 4940 ml. Plugging into Boyle's Law:
825 torr * 725 ml = P2 * 4940 ml
P2 = (825 torr * 725 ml) / 4940 ml = 207 torr
The new pressure will be 207 torr when the volume changes to 4.94 L (4940 ml).
So in summary:
(a) When volume changes to 359 ml, new pressure is 1698 torr
(b) When volume changes to 4.94 L (4940 ml), new pressure is 207 torr