Answer: To determine the number of liters of H2 gas required to synthesize 0.61 mol of CH3OH, we'll use the ideal gas law equation:
PV = nRT
Where:
P = Pressure in atm (converted from 746 mmHg)
V = Volume in liters (unknown)
n = Number of moles of gas (0.61 mol)
R = Ideal gas constant (0.0821 L·atm/(mol·K))
T = Temperature in Kelvin (converted from 86 °C)
First, let's convert the temperature from Celsius to Kelvin:
T(K) = T(°C) + 273.15
T(K) = 86 + 273.15
T(K) = 359.15 K
Now, we can rearrange the ideal gas law equation to solve for V:
V = (nRT) / P
Plugging in the values:
V = (0.61 mol * 0.0821 L·atm/(mol·K) * 359.15 K) / (746 mmHg * 1 atm/760 mmHg)
Simplifying:
V ≈ 0.148 L
Therefore, approximately 0.148 liters of H2 gas are required to synthesize 0.61 mol of CH3OH.
To find the number of liters of CO gas required under the same conditions, we use the stoichiometric coefficients of the balanced equation:
1 mol CO : 2 mol H2
Since we know the number of moles of CH3OH (0.61 mol), we can deduce that half that amount of moles of CO gas is required:
0.61 mol CH3OH * (1 mol CO / 2 mol CH3OH) = 0.305 mol CO
Using the same ideal gas law equation, we can find the volume of CO gas:
V = (nRT) / P
V = (0.305 mol * 0.0821 L·atm/(mol·K) * 359.15 K) / (746 mmHg * 1 atm/760 mmHg)
Simplifying:
V ≈ 0.074 L
Therefore, approximately 0.074 liters of CO gas are required under the same conditions.