Concentration (Molarity) = moles of solute/liters of solution
So, you need to convert grams of CO2 to moles and mL to L and then plug those numbers in.
The molar mass of CO2 is 44.01 g/mol, so 20.25g x (1 mole/44.01 g) = 0.46 moles CO2.
And 1000mL = 1L, so 675 mL x (1L/1000mL) = 0.675L solution.
Finally, M=0.46 moles CO2 / 0.675 L solution = 0.68 M.