This problem can be solved using Boyle's Law, which states that the pressure and volume of a gas are inversely proportional when temperature is constant. The formula for Boyle's Law is P1V1 = P2V2, where P1 and V1 are the initial pressure and volume, and P2 and V2 are the final pressure and volume.
Using the formula:
P1V1 = P2V2
where P1 = 5.1 atm, V1 = 6.5 L, and V2 = 4.4 L, we can solve for P2:
P2 = (P1 x V1) / V2
P2 = (5.1 atm x 6.5 L) / 4.4 L
P2 = 7.57 atm
Therefore, the new pressure inside the piston will be 7.57 atm (rounded to two decimal places).