To find the atmospheric pressure, we need to add the pressure of the water vapor to the partial pressure of the oxygen gas.
At 0°C, the vapor pressure of water is 4.58 mmHg.
So, the total pressure of the gas mixture is:
P_total = P_oxygen + P_water vapor
P_total = 741 mmHg + 4.58 mmHg
P_total = 745.58 mmHg
Therefore, the atmospheric pressure when the gas was collected was 745.58 mmHg.