Final answer:
The solubility property can be used to differentiate between potassium nitrate and silver chloride, as potassium nitrate is water-soluble and silver chloride is not.
Step-by-step explanation:
To differentiate between a 50-gram sample of solid potassium nitrate and a 50-gram sample of solid silver chloride at standard temperature and pressure (STP), one could use the solubility property of the substances. While both compounds are white solids, potassium nitrate is soluble in water, whereas silver chloride is insoluble. To separate them, one could add water to the mixture, which would dissolve the potassium nitrate while leaving the silver chloride as a precipitate.
A classic chemical reaction example illustrating the principle of solubility is the reaction between silver nitrate and sodium chloride. The reaction produces silver chloride, which is insoluble in water, thus precipitates out of the solution, while sodium nitrate remains dissolved.
Another approach could involve applying the concept of the law of conservation of mass, which demonstrates that the mass of reactants equals the mass of products, as exemplified in the reaction between sodium chloride and silver nitrate.