Since there are 10 possible characters (0 through 9) that can appear as the first character, and the probability of each character appearing is uniform, the probability of the first character being a number is 10/36 or 5/18.
Therefore, the expected number of passwords in which the first character is a number is:
500 * (5/18) = 139
So the prediction is that about 139 passwords will have a number as the first character. The answer is 139 passwords.