Answer: (A)
The concentration of benzene in the solution is 0.736 molal.
To solve the problem, we need to first calculate the moles of benzene and carbon tetrachloride in the solution:
moles of C6H6 = mass / molar mass = 16.2 g / 78.1 g/mol = 0.2075 mol
moles of CCl4 = mass / molar mass = 282 g / 154 g/mol = 1.831 mol
Next, we need to calculate the mass of the solvent (CCl4) in kilograms:
mass of CCl4 = 282 g = 0.282 kg
Finally, we can calculate the molality of the solution:
molality = moles of solute / mass of solvent (in kg) = 0.2075 mol / 0.282 kg = 0.736 mol/kg
Therefore, the answer is A) 0.736.