To calculate the pressure in the tank in atm, we can use the ideal gas law equation:
PV = nRT
Where P is the pressure, V is the volume of the tank (25.0 L), n is the total number of moles of gas (12.0 + 4.0 = 16.0 mol), R is the universal gas constant (0.0821 L*atm/mol*K), and T is the temperature in Kelvin (298 K).
First, we need to calculate the total number of moles of gas per liter of the tank:
n/V = 16.0 mol / 25.0 L = 0.64 mol/L
Then we can plug in all the values into the ideal gas law equation and solve for P:
P = (n/V) * RT = (0.64 mol/L) * (0.0821 L*atm/mol*K) * (298 K) = 15.3 atm
Therefore, the pressure in the tank is 15.3 atm.