Answer: C)Deposition (gas to solid)
Explanation: According to the phase diagram, at room temperature (25°C) and 1 atm, the sample is in the gas phase. As the temperature decreases to 80 K, it falls below the sublimation curve. T he sublimation curve represents the conditions at which a substance can change directly from a solid to a gas or from a gas to a solid without passing through the liquid phase.
Since the sample is in the gas phase at room temperature, cooling it to 80 K would cause it to go through the process of deposition, where the gas particles directly transform into a solid without first becoming a liquid. This is indicated by the section of the phase diagram below the sublimation curve.