Final answer:
The pressure in containers with equal masses of O2(g) and HBr(g), if both have the same volume and temperature, will be the same due to the ideal gas law. However, O2 molecules will have a lower average velocity compared to HBr molecules because of O2's lower molar mass relative to HBr.
Step-by-step explanation:
If equal masses of O2(g) and HBr(g) are in separate containers of equal volume and temperature, the statement that is true is: The pressures of both gases are the same. This is because, according to the ideal gas law and the kinetic molecular theory, at the same temperature and volume, equal masses of ideal gases will exert the same pressure regardless of their chemical identity. This is under the assumption that both gases behave ideally and the number of moles is the same for both gases. Additionally, gases with lighter molar masses will have higher average velocities, so O2 molecules will have a lower average velocity than HBr molecules because oxygen has a lower molar mass compared to hydrogen bromide.