Final answer:
The cathode half-reaction for the given galvanic cell involves the reduction of nitrate to nitric oxide, while the anode half-reaction involves the oxidation of copper(I) to copper(II). To calculate the cell voltage under standard conditions, standard reduction potentials for each half-reaction are needed which are not provided in this case.
Step-by-step explanation:
The given galvanic cell is powered by the redox reaction: NO3- (aq) + 4H+ (aq) + 3 Cu+ (aq) → NO(g) + 2H2O(l) + 3 Cu2+(aq).
The cathode half-reaction involves reduction and for the given reaction, it would be:
NO3- (aq) + 4H+ (aq) + 3e- → NO(g) + 2H2O(l) (reduction of nitrate to nitric oxide)
The anode half-reaction involves oxidation and is represented by:
3 Cu+ (aq) - 3e- → 3 Cu2+ (aq) (oxidation of copper(I) to copper(II))
To calculate the cell voltage under standard conditions, you would use the standard reduction potentials for each half-reaction, found in a standard reduction potential table. The cell voltage (Ecell) is calculated by subtracting the anode potential from the cathode potential (Ecell = Ecathode - Eanode). Since the exact standard reduction potentials are not provided here, we cannot calculate the cell voltage.