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When 1.00 g glucose (C6H₁2O6 180 g/mol) is combusted in an open

calorimeter with calorimeter constant 8000 J/K, the temperature rises
from 19.20 °C to 21.14 °C.
Calculate the enthalpy of combustion of AH combustion (glucose) in kJ/g

1 Answer

6 votes

Step-by-step explanation:

To calculate the enthalpy of combustion of glucose, we need to first calculate the amount of heat released by the combustion reaction.

The heat released can be calculated using the formula:

Q = CΔT

where Q is the heat released (in joules), C is the calorimeter constant (in joules per degree Celsius), and ΔT is the change in temperature of the calorimeter (in degrees Celsius).

In this case, we have:

Q = 8000 J/K x (21.14 °C - 19.20 °C) = 16000 J

This is the amount of heat released by the combustion of 1.00 g of glucose.

To calculate the enthalpy of combustion of glucose, we need to convert the amount of heat released to the enthalpy change of the reaction. We can do this using the equation:

ΔH = Q/n

where ΔH is the enthalpy change (in joules per mole), Q is the heat released (in joules), and n is the number of moles of glucose combusted.

The number of moles of glucose can be calculated using its molar mass:

n = mass/molar mass = 1.00 g / 180 g/mol = 0.00556 mol

Now we can calculate the enthalpy of combustion:

ΔH = 16000 J / 0.00556 mol = 2.88 x 10^6 J/mol

To express this in kJ/g, we can divide by the mass of glucose used:

ΔH = 2.88 x 10^6 J/mol / 1.00 g = 2.88 x 10^3 kJ/g

Therefore, the enthalpy of combustion of glucose is 2.88 x 10^3 kJ/g.

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