Answer:
1) 9.4 mol
2) 0.6 mol
3) 0.9 mol
What is Stoichiometry?
In chemical equations, unless stated otherwise, the reactants and products will theoretically always remain in stoichiometric ratios.
The stoichiometry of a reaction is the relationship between the relative quantities of products and reactants, typically a ratio of whole integers.
Consider the following chemical reaction: aA + bB ⇒ cC + dD.
The stoichiometry of reactants to products in this reaction is the ratio of the coefficients of each species: a : b : c : d.
Converting between moles and mass:
To convert from mass to moles, divide the mass present by the molar mass, resulting in the number of moles. Mathematically, the units present themselves like this:
.
Thence, the formula for moles: n = m/M, where n = number of moles, m = mass present, and M = molar mass. This formula can be easily rearranged to find mass present from molar mass and moles, or molar mass from mass and moles.
1) For the reaction C + 2H₂ → CH₄, how many moles of carbon are needed to make 150.6 g of methane, CH₄? (Molar Masses: H=1; C=12)
Stoichiometry of carbon to methane = 1 : 1.
Therefore, moles of CH₄ = moles of C. Using the formula to find moles, n(CH₄) = m/M = 150.6/(12+1×4) =9.4125 ≈ 9.4 mol
Therefore, we require 9.4 moles of carbon.
2) S + 6HNO₃ → H₂SO₄ + 6NO₂ + 2H₂O
In the above equation, how many moles of water can be made when 113 g of HNO₃ are consumed? (Molar Masses: H=1; N=14; S=32; O=16)
Stoichiometry of Nitric acid to water = 6 : 2 = 3 : 1. Therefore, we produce 1 mole of water for every 3 moles of nitric acid consumed. Hence, n(HNO₃) = m/M = 113/(1+14+16×3) = 1.79365 mol
Therefore: n(H₂O) = 1/3 × n(HNO₃) = 0.59788 mol ≈ 0.6 mol
3) 3Cu + 8HNO₃ → 3Cu(NO₃)₂ + 2NO + 4H₂O
In the above equation, how many moles of water can be made when 117.8 grams of HNO3 are consumed?
Stoichiometry of Nitric acid to water = 8 : 4 = 2 : 1. Therefore, we produce 1 mole of water for every 2 moles of nitric acid consumed. Hence, n(HNO₃) = m/M = 117.8/(1+14+16×3) = 1.86984 mol
Therefore: n(H₂O) = 1/2 × n(HNO₃) = 0.9349 mol ≈ 0.9 mol