Answer: The second reaction took place at a higher temperature
Step-by-step explanation:
Rate is affected by temperature, as higher temperatures cause the reacting molecules to have more energy.
Collision theory states that in order for a reaction to occur, each reacting molecule must collide with one another in the correct orientation and with enough energy, called the activation energy.
A higher energy caused by a higher temperature will cause the molecules to collide much more frequently, leading to a higher chance of a successful collision, and with more energy to satisfy the activation energy.
Therefore, the second reaction must have taken place at a higher temperature, since the molecules had more energy than the first reaction leading to a higher rate of reaction, and a higher rate constant.