Final answer:
H2PO4- will be the major phosphate species present after the addition of 40.0 ml of NaOH in the titration of 0.100 M phosphoric acid.
Step-by-step explanation:
When 40.0 ml of 0.100 M phosphoric acid (H3PO4) is titrated with 0.100 M NaOH, the major phosphate species present after the addition of 40.0 ml of NaOH will be H2PO4-. Phosphoric acid is a polyprotic acid, meaning it can donate multiple protons. The first equivalence point in the titration occurs when all the H3PO4 is converted to H2PO4-, and the pH at this point is approximately 4.6.