199k views
4 votes
A compound is composed of 79.4% carbon, 8.9% hydrogen, and 11.7% oxygen by weight. If it has a molar mass of 272 g/mol, what is its molecular formula?

User Anduplats
by
8.4k points

1 Answer

2 votes
To find the molecular formula of the compound, we need to first determine its empirical formula and then use the molar mass to calculate the molecular formula.

Determine the empirical formula:
Assume we have 100g of the compound, then:
Carbon = 79.4g
Hydrogen = 8.9g
Oxygen = 11.7g
Next, we need to convert the masses of each element to moles:

Carbon: 79.4g / 12.01 g/mol = 6.62 mol
Hydrogen: 8.9g / 1.01 g/mol = 8.81 mol
Oxygen: 11.7g / 16.00 g/mol = 0.73 mol
The empirical formula is the simplest whole-number ratio of the atoms, so we need to divide each mole value by the smallest mole value:

Carbon: 6.62 mol / 0.73 mol = 9.06 ≈ 9
Hydrogen: 8.81 mol / 0.73 mol = 12.06 ≈ 12
Oxygen: 0.73 mol / 0.73 mol = 1
The empirical formula is C9H12O.

Calculate the molecular formula:
To calculate the molecular formula, we need to know the molar mass of the empirical formula. The molar mass of C9H12O is:
(9 x 12.01 g/mol) + (12 x 1.01 g/mol) + (1 x 16.00 g/mol) = 136.11 g/mol
We can calculate the ratio of the molar mass of the molecular formula to the molar mass of the empirical formula:

Molecular mass / Empirical mass = 272 g/mol / 136.11 g/mol = 2
This means that the molecular formula is twice the size of the empirical formula, so we can multiply the subscripts of the empirical formula by 2 to get the molecular formula:

C9H12O x 2 = C18H24O2
Therefore, the molecular formula of the compound is C18H24O2.
User Darvas
by
8.6k points