Final answer:
Mexico is the country with the highest point known as Pico de Orizaba, which is located in the Cordillera Neovolcánica range.
Step-by-step explanation:
The country whose highest point is Pico de Orizaba is Mexico. Pico de Orizaba, also known as Citlaltépetl, is situated in the Cordillera Neovolcánica mountain range and stands as Mexico's tallest peak. This volcano is part of a volcanic range that extends approximately 620 miles across the central and southern parts of Mexico, signifying a division between North and Central America. The Cordillera Neovolcánica contains several high peaks, including Pico de Orizaba which reaches heights over 16,404 feet and is capped with snow year-round.