Final answer:
The New World settlement among the options is Tehuacan Valley, which was home to the Tehuacán culture in Mexico. It played a significant role in the development of early agriculture.
Step-by-step explanation:
The New World settlement among the given options is Tehuacan Valley. The Tehuacan Valley is located in modern-day Mexico and was home to the Tehuacán culture, which dates back to around 5000 BCE. The Tehuacán Valley is known for its agriculture and abundant plant resources, and it played a significant role in the development of early agriculture in Mesoamerica. The settlement of Tehuacan Valley is an example of a New World settlement that emerged in the Americas during ancient times.