Answer:
A. 2.65 atm.
B. 18.11 g/L.
Step-by-step explanation:
A. Determination of the pressure
Mass of N₂O = 21.3 g
Volume = 5.76 L
Temperature (T) = 111 °C
Pressure (P) =.?
First, we shall determine the number of mole in 21.3 g of dinitrogen monoxide, N₂O. This can be obtained as follow:
Mass of N₂O = 21.3 g
Molar mass of N₂O = (14×2) + 16
= 28 + 16
= 44 g/mol
Mole of N₂O =?
Mole = mass /Molar mass
Mole of N₂O = 21.3/44
Mole of N₂O = 0.484 mole
Next, we shall convert 111°C to Kelvin temperature. This can be obtained as follow:
T(K) = T(°C) + 273
Temperature (T) = 111 °C
Temperature (T) = 111 °C + 273
Temperature (T) = 384 K
Finally, we shall determine the pressure. This can be obtained as follow:
Number mole of N₂O = 0.484 mole
Volume = 5.76 L
Temperature (T) = 384 K
Gas constant (R) = 0.0821 atm.L/Kmol
Pressure (P) =.?
PV = nRT
P × 5.76 = 0.484 × 0.0821 × 384
Divide both side by 5.76
P = (0.484 × 0.0821 × 384) / 5.76
P = 2.65 atm
B. Determination of the density of CFCl₃
Temperature (T) = 157°C
Pressure (P) = 4.65 atm.
Density of CFCl₃ =?
First, we shall determine the molar mass of CFCl₃. This can be obtained as follow:
Molar mass of CFCl₃ = 12 + 19 + (35.5×3)
= 12 + 19 + 106.5
= 137.5 g/mol
Next, we shall convert 157°C to Kelvin temperature. This can be obtained as follow:
T(K) = T(°C) + 273
Temperature (T) = 157 °C
Temperature (T) = 157 °C + 273
Temperature (T) = 430 K
Finally, we shall determine the density of CFCl₃. This can be obtained as follow:
Temperature (T) = 430 K
Pressure (P) = 4.65 atm.
Molar mass of CFCl₃ (M) = 137.5 g/mol
Gas constant (R) = 0.0821 atm.L/Kmol
Density (D) of CFCl₃ =?
D = PM / RT
D = (4.65 × 137.5) / (0.0821 × 430)
D = 18.11 g/L