Final answer:
Chitin is a nitrogen-containing polysaccharide that is different from other polysaccharides due to the presence of nitrogen in its structure. The atom type unique to chitosan, a component of chitin, is Nitrogen.
Step-by-step explanation:
Chitin is a unique polysaccharide found in the exoskeleton of invertebrates, such as insects and crustaceans, and in the cell walls of fungi.
It is composed of repeating units of N-acetyl-β-d-glucosamine, which is a modified form of sugar. What distinguishes chitin from other polysaccharides is the presence of nitrogen within its structure, specifically within the acetylamine group of each N-acetylglucosamine unit. Therefore, the atom type found in chitosan that is not present in other monosaccharides is Nitrogen (A).