Final answer:
The correct sign to be posted on the storage closet containing radioactive materials is 'Caution: radioactive materials'.
Step-by-step explanation:
The correct sign to be posted on the locked storage closet next to the radiopharmacy would be a. Caution: radioactive materials. The measured exposure rate of 3 mR/hr indicates the presence of radioactive materials, which require special safety precautions to be taken. The sign serves as a warning to anyone entering the area to be cautious and aware of the potential radiation hazards.