Final answer:
In anaerobic muscle metabolism, the least likely event to occur is phosphorylation of ADP within the electron transport chain.
Step-by-step explanation:
In anaerobic muscle metabolism, the least likely event to occur is b) phosphorylation of ADP within the electron transport chain. Anaerobic metabolism, also known as glycolysis, occurs in the absence of oxygen and is an inefficient process for generating ATP. During glycolysis, glucose is broken down to produce ATP and lactic acid. The electron transport chain, which requires oxygen, is not involved in anaerobic metabolism.