Final answer:
On a mountaintop, water boils at a lower temperature because the equilibrium water vapor pressure equals the atmospheric pressure at a lower temperature. As a result, the boiling point of water is reduced from 100°C at sea level to 90°C.
Step-by-step explanation:
The boiling point of water is affected by external pressure. At higher altitudes, the atmospheric pressure is lower, which leads to a lower boiling point. For example, on a mountaintop, water boils at 90°C instead of 100°C at sea level. This occurs because the equilibrium water vapor pressure equals the atmospheric pressure at a lower temperature.