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What is the effect on the rate of using four times the amount of solvent and increasing the temperature by 10°c in an Sn₁ reaction? assume all other variables in the reaction (other than the one(s) mentioned) remain constant.

options:
a. Reaction rate stays the same
b.4 x rate
c.1/4 rate
d.2 x rate
e.1/2 rate

User Gorkk
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1 Answer

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Final answer:

In an SN1 reaction, increasing the solvent amount fourfold does not affect the reaction rate, while increasing the temperature by 10°C doubles the reaction rate. Therefore, the overall effect on the reaction rate would be a doubling of the rate. The correctanswer is d.2 x rate.

Step-by-step explanation:

The question is about the impact on the reaction rate of an SN1 reaction when the amount of solvent is increased fourfold and the temperature is increased by 10°C.

In an SN1 reaction, the rate is typically dependent on the concentration of the substrate, not on the concentration of the solvent; thus, increasing the solvent would not directly affect the reaction rate. Increasing the temperature by 10°C, however, usually increases the rate of reaction.

Given the assumption that the rate of a reaction doubles with a 10°C increase in temperature, the effect of increasing the temperature alone would be to double the rate of the reaction.

Combining both effects, the fourfold increase in solvent (which does not affect the rate for an SN1 reaction) and the increase of temperature by 10°C (which doubles the rate), the overall impact would be to double the reaction rate.

User Aean
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