Final answer:
The overall free energy change (ΔG) for the reaction A⇌D is calculated by summing up the individual ΔG values for each step of the path, resulting in a total ΔG of -9.7 kJ/mol.
Step-by-step explanation:
To calculate the free energy change (ΔG) for the overall reaction from A to D, we simply add the free energy changes of the individual steps in the reaction pathway.
- The free energy change for A to B is 14.3 kJ/mol.
- The free energy change for B to C is -30.2 kJ/mol.
- The free energy change for C to D is 6.20 kJ/mol.
By adding these values together, we can find the overall free energy change:
14.3 kJ/mol (A to B) - 30.2 kJ/mol (B to C) + 6.20 kJ/mol (C to D) = -9.7 kJ/mol (A to D)
Therefore, the ΔG for the overall reaction A⇌D is -9.7 kJ/mol.