Final answer:
The concentration of oxalate in the unknown solution is 0.0287 M.
Step-by-step explanation:
To find the concentration of the oxalate in the unknown solution, we can use the concept of stoichiometry and the equation for the reaction between permanganate and oxalate:
2MnO4¯(aq) + 5H2C2O4(aq) + 6H+(aq) → 10CO2(g) + 2Mn2+(aq) + 8H2O(l)
From the equation, we can see that 2 moles of MnO4¯ react with 5 moles of H2C2O4. Given that it takes 35.44 mL of 0.0205 M permanganate solution to react with 25 mL of the unknown oxalate solution, we can set up the following equation:
Moles of MnO4¯ = Moles of H2C2O4
(0.0205 mol/L)(35.44 mL) = (x mol/L)(25 mL)
Solving for x, the concentration of oxalate, we get:
x = (0.0205 mol/L)(35.44 mL) / (25 mL)
x = 0.0287 M
The concentration of oxalate in the unknown solution is 0.0287 M.