Final answer:
Calorimetry is a method to determine the heat of a reaction (ΔH) by measuring temperature changes in a constant-pressure environment, taking into account the mass and specific heat capacity of the aqueous solution.
Step-by-step explanation:
The heat of reaction, or enthalpy change (ΔH), in an aqueous solution can be determined through calorimetry, which involves measuring temperature changes in a chemical reaction to calculate the heat absorbed or released. For example, the reaction between NaOH and HCl in an aqueous solution results in a temperature increase, indicating an exothermic reaction. By using the specific heat capacity of water (4.18 J/g°C) and the mass of the solution, one can calculate the heat (q) using the formula q = m⋅c⋅ΔT, where m is the mass of the solution, c is the specific heat capacity, and ΔT is the change in temperature.
To carry out a constant-pressure calorimetry experiment, one must ensure no heat is lost to the surroundings or absorbed by the calorimeter itself. By mixing known quantities of different reagents at known temperatures and measuring the temperature change when the reaction occurs, we can determine the enthalpy change for the reaction. The conditions must be such that the resulting solution reaches thermal equilibrium, where the net heat change equals zero, indicating all of the heat released by the reaction has been absorbed by the solution.